Summer 2004: Jolie and Pitt meet on the set of their action movie Mr & Mrs Smith and rumours circulate that the couple "fell in love" during filming.Pitt was married to actress Jennifer Aniston at the time but he has always denied having an affair with Jolie.According to TMZ, Jolie, 41, is seeking physical custody of their six children and has asked the judge to allow Pitt, 52, visitation rights.Sources allege that the Maleficent actress was unhappy with the way Pitt was parenting their children, causing a rift between the couple.The .6m fee collectively earned from selling the child's first photos to OK!And Hello magazine were donated to charities to aid the education and development of African children.The actress also said at the time: "To be intimate with a married man, when my own father cheated on my mother, is not something I could forgive."January 2005: Pitt and Aniston announce their split after five years of marriage.
As Hollywood mourns the end of what appeared to be one of the strongest showbiz couples, IBTimes UK takes a look back at Brangelina's highly-publicised love story.Angelina Jolie and Brad Pitt were one of the most beloved couples in showbiz but the pair have decided to divorce.Two years after they tied the knot in a romantic wedding at their French home, Brangelina are parting ways with Jolie reportedly citing "irreconcilable differences".October 2006: Pitt states that he and Jolie have agreed to marry only when same-sex couples are given the right to legally marry in the US.
October 2005: Pitt and Aniston's divorce is finalised.11 January 2006: Jolie confirms she is pregnant with her and Pitt's first child, telling People: "Yes, I'm pregnant." 16 January 2006: Jolie legally changes the last names of her adopted children from Jolie to Pitt.The actor officially adopts Maddox and Zahara soon after.: Jolie gives birth to the couple's first biological child in Swakopmund, Namibia and name her Shiloh Nouvel.